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    Nerylacetate
    Nerylacetate
    Information
    CAS No. 141-12-8 Price $30 / 20mg
    Catalog No.CFN93088Purity>=98%
    Molecular Weight196.3Type of CompoundMonoterpenoids
    FormulaC12H20O2Physical DescriptionOil
    Download     COA    MSDSSimilar structuralComparison (Web)
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    Biological Activity
    Description: Nerylacetate and 1,5-dienes geranyl acetate are catalyzed to the cis-2,5-bis(hydroxymethyl)tetrahydrofurans 3 and 4 by OsO4.
    Nerylacetate Description
    Source: Found in citrus, kumquat and pummelo peel oils, ginger, cardamon, clary sage and myrtle.
    Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
    Storage: Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

    Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

    Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com

    After receiving: The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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    Cell. 2018 Jan 11;172(1-2):249-261.e12.
    doi: 10.1016/j.cell.2017.12.019.

    PMID: 29328914

    Mol Cell. 2017 Nov 16;68(4):673-685.e6.
    doi: 10.1016/j.molcel.2017.10.022.

    PMID: 29149595

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    doi: 10.1038/s41598-017-17427-6.

    PMID: 29230013

    Molecules. 2017 Oct 27;22(11). pii: E1829.
    doi: 10.3390/molecules22111829.

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    J Cell Biochem. 2018 Feb;119(2):2231-2239.
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    Calculate Dilution Ratios(Only for Reference)
    1 mg 5 mg 10 mg 20 mg 25 mg
    1 mM 5.0942 mL 25.4712 mL 50.9424 mL 101.8849 mL 127.3561 mL
    5 mM 1.0188 mL 5.0942 mL 10.1885 mL 20.377 mL 25.4712 mL
    10 mM 0.5094 mL 2.5471 mL 5.0942 mL 10.1885 mL 12.7356 mL
    50 mM 0.1019 mL 0.5094 mL 1.0188 mL 2.0377 mL 2.5471 mL
    100 mM 0.0509 mL 0.2547 mL 0.5094 mL 1.0188 mL 1.2736 mL
    * Note: If you are in the process of experiment, it's need to make the dilution ratios of the samples. The dilution data of the sheet for your reference. Normally, it's can get a better solubility within lower of Concentrations.
    Protocol
    Structure Identification:
    Tetrahedron Letters, 1998 , 39 (52) :9781-4.
    OsO4-Catalyzed oxidative cyclization of geranyl and neryl acetate to cis-2,5-bis(hydroxymethyl)tetrahydrofurans[Reference: WebLink]

    METHODS AND RESULTS:
    OsO4 catalyzes the oxidative cyclization of the 1,5-dienes geranyl acetate (1) and Nerylacetate (2) to the cis-2,5-bis(hydroxymethyl)tetrahydrofurans 3 and 4 respectively, in the presence of NaIO4 as cooxidant in DMF. The reaction is stereospecific and proceeds with the sequential syn addition to both double bonds of the starting materials. The observed stereoselectivity can be explained by invoking the intermediacy of a square-based pyramidal osmium (VI) diester (5) that has been isolated and characterized.
    CONCLUSIONS:
    Evidence is reported that this substance is indeed an intermediate in the transformation of 1 to 3.