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    6-epi-Albrassitriol
    6-epi-Albrassitriol
    Information
    CAS No. 178456-58-1 Price
    Catalog No.CFN89042Purity>=98%
    Molecular Weight254.37Type of CompoundSesquiterpenoids
    FormulaC15H26O3Physical DescriptionPowder
    Download     COA    MSDSSimilar structuralComparison (Web)
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    Description: 6-epi-Albrassitriol is a natural product from A spergillussp.
    6-epi-Albrassitriol Description
    Source: From A spergillussp.
    Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
    Storage: Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

    Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

    Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com

    After receiving: The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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    Recently, ChemFaces products have been cited in many studies from excellent and top scientific journals

    Cell. 2018 Jan 11;172(1-2):249-261.e12.
    doi: 10.1016/j.cell.2017.12.019.
    IF=36.216(2019)

    PMID: 29328914

    Cell Metab. 2020 Mar 3;31(3):534-548.e5.
    doi: 10.1016/j.cmet.2020.01.002.
    IF=22.415(2019)

    PMID: 32004475

    Mol Cell. 2017 Nov 16;68(4):673-685.e6.
    doi: 10.1016/j.molcel.2017.10.022.
    IF=14.548(2019)

    PMID: 29149595

    ACS Nano. 2018 Apr 24;12(4): 3385-3396.
    doi: 10.1021/acsnano.7b08969.
    IF=13.903(2019)

    PMID: 29553709

    Nature Plants. 2016 Dec 22;3: 16206.
    doi: 10.1038/nplants.2016.205.
    IF=13.297(2019)

    PMID: 28005066

    Sci Adv. 2018 Oct 24;4(10): eaat6994.
    doi: 10.1126/sciadv.aat6994.
    IF=12.804(2019)

    PMID: 30417089
    Calculate Dilution Ratios(Only for Reference)
    1 mg 5 mg 10 mg 20 mg 25 mg
    1 mM 3.9313 mL 19.6564 mL 39.3128 mL 78.6256 mL 98.282 mL
    5 mM 0.7863 mL 3.9313 mL 7.8626 mL 15.7251 mL 19.6564 mL
    10 mM 0.3931 mL 1.9656 mL 3.9313 mL 7.8626 mL 9.8282 mL
    50 mM 0.0786 mL 0.3931 mL 0.7863 mL 1.5725 mL 1.9656 mL
    100 mM 0.0393 mL 0.1966 mL 0.3931 mL 0.7863 mL 0.9828 mL
    * Note: If you are in the process of experiment, it's need to make the dilution ratios of the samples. The dilution data of the sheet for your reference. Normally, it's can get a better solubility within lower of Concentrations.
    Protocol
    Structure Identification:
    Nat Prod Res. 2013;27(9):809-17.
    Synthesis of (-)-albrassitriol and (-)-6-epi-albrassitriol from (+)-larixol.[Pubmed: 22794273 ]
    A novel synthesis of natural drimanic compounds, (-)-albrassitriol (2) and (-)-6-epi-Albrassitriol (3), has been carried out starting from an easily available labdane diterpenoid, (+)-larixol (1).
    METHODS AND RESULTS:
    In a two-step procedure, (+)-larixol (1) was converted into 14,15-bisnorlab-7-ene-6,13-dione (9), which was then submitted to a Norrish type II photochemical degradation yielding drim-7,9(11)-diene-6-one (10), whose treatment with OsO4 led selectively to the formation of drim-7-ene-9α,11-diol-6-one (12). The same compound was obtained by selective epoxidation of the C(9)-C(11) double bond in drim-7,9(11)-diene-6-one (10) with monoperphtalic acid. Treatment of the resulting mixture of α- and β-epoxides (13 and 14) with HClO4 yielded drim-7-ene-9α,11-diol-6-one (12). Reduction of the C6-carbonyl group in drim-7-ene-9α,11-diol-6-one (12) with LiAlH4 afforded (-)-albrassitriol (2) and (-)-6-epi-Albrassitriol (3), 12.4% and 13.6% overall yields, respectively.